Jp. Guillemet et al., CRYSTALLIZATION OF AMORPHOUS THIN LPCVD SI FILMS - IN-SITU TEM MEASUREMENT OF NUCLEATION AND GRAIN-GROWTH RATES, Materials science & engineering. A, Structural materials: properties, microstructure and processing, 173(1-2), 1993, pp. 377-380
The influence of deposition conditions on the solid phase crystallisat
ion of as-deposited amorphous Si layers obtained by low pressure chemi
cal vapor deposition has been investigated by ''in situ'' isothermal a
nnealing in a transmission electron microscope. Both nucleation and gr
ain growth rates have been determined. Growth process was found to be
linear with an activation energy of 2.4 eV. Nucleation kinetics have b
een calculated from both the size of the crystallites and the grain gr
owth rates. Final grain size has been shown to depend on deposition pr
ocedure.