POLYMORPHIC TRANSFORMATIONS OF TITANIA INDUCED BY BALL-MILLING

Citation
S. Begincolin et al., POLYMORPHIC TRANSFORMATIONS OF TITANIA INDUCED BY BALL-MILLING, Philosophical magazine letters, 69(1), 1994, pp. 1-7
Citations number
25
Categorie Soggetti
Physics, Condensed Matter
ISSN journal
09500839
Volume
69
Issue
1
Year of publication
1994
Pages
1 - 7
Database
ISI
SICI code
0950-0839(1994)69:1<1:PTOTIB>2.0.ZU;2-P
Abstract
The high-pressure modification of TiO2 with an alpha-PbO2-type structu re is formed transiently during room-temperature grinding of anatase. Rutile is the only phase present after prolonged ball milling. These e xperimental results are at variance with reports of a direct transform ation of anatase into rutile by room-temperature grinding.