Bv. Ratnakumar et al., A NEW REFERENCE ELECTRODE FOR NA MCL(2) BATTERIES/, Journal of the Electrochemical Society, 140(12), 1993, pp. 120000171-120000172
The use of aluminum as a reference electrode in the neutral and basic
chloroaluminate molten salts poses certain problems related to the unc
ertainty and irreproducibility in the measured electrode potentials as
well as lack of stability in tong-term studies. A new reference elect
rode based on an insoluble transition metal chloride, e.g., NiCl2 is p
roposed to address these problems. Ni/NiCl2 forms an electrode of the
second kind with high exchange current density and long durability and
would be an ideal choice for the electrochemical studies in neutral a
nd basic chloroaluminate melts, including Na/NiCl2 cells.