DYNAMIC BEHAVIOR OF POWER COMPENSATED DIFFERENTIAL SCANNING CALORIMETERS .2. THE SIGNAL FLOW

Citation
Jek. Schawe et al., DYNAMIC BEHAVIOR OF POWER COMPENSATED DIFFERENTIAL SCANNING CALORIMETERS .2. THE SIGNAL FLOW, Thermochimica acta, 229, 1993, pp. 37-52
Citations number
10
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00406031
Volume
229
Year of publication
1993
Pages
37 - 52
Database
ISI
SICI code
0040-6031(1993)229:<37:DBOPCD>2.0.ZU;2-T
Abstract
The dynamic behaviour of the measured signal of a power compensated DS C is studied in terms of linear response taking into account the measu ring system, the sample, the reference, the control circuits, the heat transport coefficients and the heat losses. As a result it is shown t hat the apparatus (or Green's) function of the DSC (including sample a nd heat transfer) is different from that necessary to desmear the samp le heat flow. The quality of the extracted Green's function is discuss ed for different measuring conditions.