U. Kramm, ISOTOPE EVIDENCE FOR IJOLITE FORMATION BY FENITIZATION - SR-ND DATA OF IJOLITES FROM THE TYPE LOCALITY IIVAARA, FINLAND, Contributions to Mineralogy and Petrology, 115(3), 1994, pp. 279-286
Ijolites from the type locality at Iivaara, Finland, form a continuous
series of magmatic rocks ranging from urtites to melteigites. Both Ni
and Cr, but also the large ion lithophile light-rare-earth elements,
Zr, Hf, Nb, Rb, Sr and Ba are low in concentration. The Nd contents eq
ual those of the neighboring fenites, Sr is distinctly less abundant,
and there is no significant Eu anomaly. The Nd-143/Nd-144 and Sr-87/Sr
-86 of the ijolites demonstrate a systematic covariation between the d
ata of carbonatites from the Kola Alkaline Province (epsilon(Sr) - 13.
8, epsilon(Nd) + 5.6) and those of the fenites at Iivaara (epsilon(Sr)
+ 132.9, epsilon(Nd)24. 7), with epsilon(Sr) varying from + 0.3 to 23.9 and epsilon(Nd) varying from - 9.2 to - 19.3. The trace element a
bundances and the isotopic data give evidence for a crystallization of
the rocks from a liquid generated by melting (rheomorphism) of high-g
rade fenitized country rocks rather than from a primary mantle-derived
magma which was contaminated at crustal levels. The fenitization of w
all rocks preceding the ijolite magma formation was element selective.
Mixing of elements during the fenitization process between the design
ated components carbonatite (or derivative fenitizing fluid) and wall
rock should have been dynamical depending on the stability of the wall
rock mineral assemblages in contact with the fenitizing fluids, the m
igration velocity of these fluids, and their capacity of the respectiv
e elements. Such dynamical mixing explains best the variation of the i
sotope ratios without systematic covariation of the respective element
concentrations.