A study on negative ion formation in the scattering of a proton beam f
rom two monolayers of Ba on Ag(111) surface is presented. The dependen
ce of the negative ion yield on the polar scattering angle and azimuth
al orientation of the crystal has been determined for beam energies fr
om 500 to 1000 eV. In addition the yield of fast neutrals has been det
ermined. Based upon a shadowing and blocking analysis of the angular d
istributions of the H- ions, it can be concluded that the Ba overlayer
shows the same crystalline structure as the Ag(111) substrate. The re
corded negative ion fractions can be explained by a simple model descr
ibing resonant charge transfer calculated by the non-perturbative CAM
method and taking into account the parallel velocity effect.