SYNTHESIS AND PROPERTIES OF TA(CO)(4)(DPPE), THE 1ST STABLE MONONUCLEAR TANTALUM(O) CARBONYL COMPOUND

Authors
KOESLAG MAD BAIRD MC
Citation
Mad. Koeslag et Mc. Baird, SYNTHESIS AND PROPERTIES OF TA(CO)(4)(DPPE), THE 1ST STABLE MONONUCLEAR TANTALUM(O) CARBONYL COMPOUND, Organometallics, 13(1), 1994, pp. 11-12
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
1
Year of publication
1994
Pages
11 - 12
Database
ISI
SICI code
0276-7333(1994)13:1<11:SAPOTT>2.0.ZU;2-8
Abstract
Reaction of the hydride TaH(CO)4(dppe) (dppe = 1,2-bis(diphenylphosphi no)ethane) in benzene with the tris(p-tert-butylphenyl)methyl radical results in abstraction of the metal-bonded hydrogen atom and formation of tris(p-tert-butylphenyl)methane and the 17-electron compound Ta(CO )4(dppe). The latter is the first tantalum(0) carbonyl compound to be synthesized and studied.