(2,5-NORBORNADIENE)RHODIUM(I) COMPLEXES WITH BIS(AZOL-1-YL)METHANE AND TRIS (AZOL-1-YL)METHANE

Authors
BALLESTEROS P LOPEZ C LOPEZ C CLARAMUNT RM JIMENEZ JA CANO M HERAS JV PINILLA E MONGE A
Citation
P. Ballesteros et al., (2,5-NORBORNADIENE)RHODIUM(I) COMPLEXES WITH BIS(AZOL-1-YL)METHANE AND TRIS (AZOL-1-YL)METHANE, Organometallics, 13(1), 1994, pp. 289-297
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
1
Year of publication
1994
Pages
289 - 297
Database
ISI
SICI code
0276-7333(1994)13:1<289:(CWBA>2.0.ZU;2-K
Abstract
Reactions of clo[2.2.1]hepta-2,5-diene]bis(mu-chloro)dirhodium, [RhCl- (NBD)]2, with bis- and tris(azolyl)methanes have been performed in met hanol and acetone with 1:1 and 1:2 [RhCl(NBD)]2/ligand molar ratios. T he structures of the complexes have been characterized by infrared and H-1 and C-13 NMR spectroscopy as well as X-ray diffraction analysis. Cationic species have been evidenced in the solid state while equilibr ia between cationic and neutral species have been established in solut ion.