A NEW TRICYCLIC SULFUR-RICH PHOSPHANE

Authors
BLACHNIK R LONNECKE P
Citation
R. Blachnik et P. Lonnecke, A NEW TRICYCLIC SULFUR-RICH PHOSPHANE, Zeitschrift fur anorganische und allgemeine Chemie, 620(1), 1994, pp. 167-172
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
620
Issue
1
Year of publication
1994
Pages
167 - 172
Database
ISI
SICI code
0044-2313(1994)620:1<167:ANTSP>2.0.ZU;2-G
Abstract
From the products of the reaction of P4S3 with tert-Butyliodide the co mpound (t-Bu(S)P)2P4S3 was isolated in low yield. The compound is stab le and has a structure related to the hydrocarbon brexane. By reaction with triphenylphosphin the compounds (t-BuP)(t-Bu(S)P)P4S, and (t-BUP )2P4S3 were obtained. The P-31-nmr spectra of all compounds were solve d and used to determine the structure of the molecules. A complete set of P-31-nmr data is given.