THE CRYSTAL-STRUCTURE OF THE SUPRAMOLECULAR CADMIUMCYANIDE-HEXAMETHYLENETETRAMINE ADDUCT [CD(CN)2 2 3C6H12N4]/

Authors
PICKARDT J GONG GT
Citation
J. Pickardt et Gt. Gong, THE CRYSTAL-STRUCTURE OF THE SUPRAMOLECULAR CADMIUMCYANIDE-HEXAMETHYLENETETRAMINE ADDUCT [CD(CN)2 2 3C6H12N4]/, Zeitschrift fur anorganische und allgemeine Chemie, 620(1), 1994, pp. 183-186
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
620
Issue
1
Year of publication
1994
Pages
183 - 186
Database
ISI
SICI code
0044-2313(1994)620:1<183:TCOTSC>2.0.ZU;2-2
Abstract
Single crystals of a new compound in the system Cd(CN)2-hexamethylenet etramine (HMTA) with the composition [Cd(CN)2 . 2/3C6H12N4] were obtai ned by crystallization from an aqueous solution containing Cd(CN)2 and HMTA. The structure consists of a ''supramolecular'' network of -Cd-C N-Cd- and -Cd-HMTA-Cd-chains. The structure is compared with that of a n already known compound [Cd(CN)2 . 1/3C6H12N4].