NMR SPECTROSCOPY OF ORGANOLITHIUM COMPOUNDS .15. 2-DIMENSIONAL LI-6,H-1-NMR SHIFT CORRELATION BY MULTIPLE-QUANTUM SPECTROSCOPY AND POLARIZATION TRANSFER - NEW TOOLS FOR STRUCTURAL RESEARCH IN THE FIELD OF ORGANOLITHIUM COMPOUNDS

Authors
MONS HE GUNTHER H MAERCKER A
Citation
He. Mons et al., NMR SPECTROSCOPY OF ORGANOLITHIUM COMPOUNDS .15. 2-DIMENSIONAL LI-6,H-1-NMR SHIFT CORRELATION BY MULTIPLE-QUANTUM SPECTROSCOPY AND POLARIZATION TRANSFER - NEW TOOLS FOR STRUCTURAL RESEARCH IN THE FIELD OF ORGANOLITHIUM COMPOUNDS, Chemische Berichte, 126(12), 1993, pp. 2747-2751
Citations number
44
Categorie Soggetti
Chemistry
Journal title
Chemische Berichte → ACNP
ISSN journal
00092940
Volume
126
Issue
12
Year of publication
1993
Pages
2747 - 2751
Database
ISI
SICI code
0009-2940(1993)126:12<2747:NSOOC.>2.0.ZU;2-D
Abstract
Sizable scalar Li-6,H-1 spin-spin coupling constants have been observe d for the new dilithio compound (Z)-2-lithio-1-(o-lithiophenyl)ethene (3) which allow an assignment of the two nonequivalent Li-6 resonance signals measured for the dimer of 3. Two-dimensional Li-6,H-1 shift co rrelation experiments based on multiple quantum spectroscopy as well a s on polarization transfer are introduced as new tools for structural research in the field of organolithium compounds.