SYNTHESES AND PROPERTIES OF MIXED-LIGAND COMPLEXES OF DIORGANOTIN(IV).4. ISOPROPOXY DIBUTYLTIN BETA-DIKETONATES AND BETA-KETOESTERS

Authors
CHATURVEDI A NAGAR PN SRIVASTAVA G
Citation
A. Chaturvedi et al., SYNTHESES AND PROPERTIES OF MIXED-LIGAND COMPLEXES OF DIORGANOTIN(IV).4. ISOPROPOXY DIBUTYLTIN BETA-DIKETONATES AND BETA-KETOESTERS, Boletin de la Sociedad Chilena de Quimica, 38(4), 1993, pp. 265-270
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Boletin de la Sociedad Chilena de Quimica → ACNP
ISSN journal
03661644
Volume
38
Issue
4
Year of publication
1993
Pages
265 - 270
Database
ISI
SICI code
0366-1644(1993)38:4<265:SAPOMC>2.0.ZU;2-Z
Abstract
Complexes of the type [(PrO)-O-i]Bu(2)Sn[RCOCHCOR'] (where R = R' = Me ; R = Me, R' = Ph; R = R' = Ph; R = Me, R' = OEt) and Bu(2)Sn[RCOCHCOR '](2) (where R = CH3; R' = OEt) have been synthesized by the reactions of dibutyltin diisopropoxide with beta-diketones and beta-ketoester i n 1:1 and 1:2 molar ratio, respectively. These have been characterised by elemental analysis, molecular weight measurements, IR and NMR (H-1 , C-13 and Sn-119) spectral studies.