OBSERVATION OF A NEW ORDERED PHASE IN ALXIN1-XAS ALLOY AND RELATION BETWEEN ORDERING STRUCTURE AND SURFACE RECONSTRUCTION DURING MOLECULAR-BEAM-EPITAXIAL GROWTH
A. Gomyo et al., OBSERVATION OF A NEW ORDERED PHASE IN ALXIN1-XAS ALLOY AND RELATION BETWEEN ORDERING STRUCTURE AND SURFACE RECONSTRUCTION DURING MOLECULAR-BEAM-EPITAXIAL GROWTH, Physical review letters, 72(5), 1994, pp. 673-676
A new phase with spontaneous atomic ordering on the sublattice is foun
d in Al0.48In0.52As grown on exact (001) InP substrate by molecular-be
am epitaxy. The atomic arrangement is a periodic sequence of {111} A p
lanes in a unit of AlxIn1-x/AlyIn1-y/AlzIn1-z on the group-III sublatt
ice. The surface reconstruction during growth is (2x3). A CuPt-type or
dered phase is observed in crystals grown at higher temperatures, wher
e the reconstruction is (2 x 1). This correlation with respect to peri
odicity and direction between the reconstructions and the types of ord
ered phase unequivocally demonstrates that surface reconstruction play
s a central role in ordered structure formation. Band-gap reductions o
f approximately 80 and approximately 30 meV are observed for the new o
rdered phase and the CuPt-type phase, respectively.