DIRECT SYNTHESIS AND CRYSTAL-STRUCTURE OF LEAD(II) IODIDE COMPLEX WITH ETHANOLAMINE

Authors
SKOPENKO VV KOKOZAY VN POLYAKOV VR SIENKIEWICZ AV
Citation
Vv. Skopenko et al., DIRECT SYNTHESIS AND CRYSTAL-STRUCTURE OF LEAD(II) IODIDE COMPLEX WITH ETHANOLAMINE, Polyhedron, 13(1), 1994, pp. 15-18
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
1
Year of publication
1994
Pages
15 - 18
Database
ISI
SICI code
0277-5387(1994)13:1<15:DSACOL>2.0.ZU;2-T
Abstract
The complex Pb-6(Ea)(6)(HEa)(2)I-6, (where HEa is ethanolamine) was ob tained by interaction of lead oxide powder and ammonium iodide in etha nolamine. The crystal structure of the compound was determined by X-ra y crystallography. The crystal is formed by [Pb-2(HEa)(2)(Ea)(2)](2+) and [Pb-4(Ea)(4)](4+) cations and iodide anions. Bidentate aminoethoxo groups are coordinated to lead via the oxygen and nitrogen atoms, whe reas monodentate aminoethanol molecules are attached through the nitro gen atoms only.