SPECTROSCOPY AND STRUCTURE OF COMPLEXES WITH LN-N BONDS .1. SPECTROSCOPY OF CRYSTALS OF NEODYMIUM COMPLEXES WITH NITRILOTRIACETIC AND ALPHA-PICOLINIC ACIDS
P. Starynowicz et K. Bukietynska, SPECTROSCOPY AND STRUCTURE OF COMPLEXES WITH LN-N BONDS .1. SPECTROSCOPY OF CRYSTALS OF NEODYMIUM COMPLEXES WITH NITRILOTRIACETIC AND ALPHA-PICOLINIC ACIDS, Polyhedron, 13(1), 1994, pp. 109-112
Absorption spectra of single crystals of K-3[Nd(NTA)(2)(H2O)].5H(2)O a
nd (C2N2H10) [Nd-2(alpha-picolinate)(8)].6H(2)O were measured. The res
ults are analysed in terms of Judd-Ofelt theory. The role of dynamic (
polarization) mechanism contribution to the oscillator strengths is di
scussed.