Exotic atoms like muonic atoms can be formed either by direct capture,
often called Coulomb capture, or by muon transfer from a muonic hydro
gen atom. The first estimates for the formation predicted, for both me
chanisms, probabilities approximately proportional to the charge numbe
r Z. The experiments did not confirm such a simple Z-dependence. In di
rect capture, it turned out that the chemical bond played a decisive r
ole, at least for lighter elements. In the formation via transfer, sur
prising data were obtained not only for heteroatomic molecules but als
o for noble gases. Whereas for direct capture, a model is able to repr
oduce quite satisfactorily a great number of measured capture ratios,
including those in hydrogen compounds, the formation via transfer seem
s to put completely different and more fundamental questions.