LOW-TEMPERATURE FORMATION OF MGH2 IN TI0.6ZR0.4MN0.8CRCU0.2 MG/

Citation
S. Orimo et al., LOW-TEMPERATURE FORMATION OF MGH2 IN TI0.6ZR0.4MN0.8CRCU0.2 MG/, Journal of alloys and compounds, 203(1-2), 1994, pp. 61-65
Citations number
27
Categorie Soggetti
Chemistry Physical","Metallurgy & Mining","Material Science
ISSN journal
09258388
Volume
203
Issue
1-2
Year of publication
1994
Pages
61 - 65
Database
ISI
SICI code
0925-8388(1994)203:1-2<61:LFOMIT>2.0.ZU;2-D
Abstract
We have investigated the hydriding properties and microstructures of t he new composite material Ti0.6Zr0.4Mn0.8CrCu0.2/Mg which contains ele mental Mg as a binder. The hydriding properties of the host compound a re improved owing to the Mg reduction effect in the process of heat tr eatment. In addition, we observed that in the process of heat treatmen t the Cu in the host compound Ti0.6Zr0.4Mn0.8CrCu0.2 diffuses into the Mg region and Mg2Cu is formed. After hydriding and dehydriding cycles , hydrogen in the host compound diffuses into the Mg region through th e Mg2Cu phase. Consequently, MgH2 is formed even at temperatures below 373 K under hydrogen pressures of less than 1 MPa.