SYNTHESIS AND CRYSTAL-STRUCTURE OF THE NOVEL CYCLOPALLADATED COMPLEX E-2-THIOLATE)-BIS[(N,N-DIMETHYLBENZYLAMINE-C(2),N) PALLADIUM(II)]

Authors
CAIRES ACF MAURO AE SANTOS RHD GAMBARDELLA MTP LECHAT JR
Citation
Acf. Caires et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF THE NOVEL CYCLOPALLADATED COMPLEX E-2-THIOLATE)-BIS[(N,N-DIMETHYLBENZYLAMINE-C(2),N) PALLADIUM(II)], Gazzetta chimica italiana, 123(9), 1993, pp. 495-497
Citations number
24
Categorie Soggetti
Chemistry
Journal title
Gazzetta chimica italiana → ACNP
ISSN journal
00165603
Volume
123
Issue
9
Year of publication
1993
Pages
495 - 497
Database
ISI
SICI code
0016-5603(1993)123:9<495:SACOTN>2.0.ZU;2-M
Abstract
The compound )-bis[(N,N-dimethylbenzylamine-C2,N)palladium(II)] was sy nthesized and studied by IR, NMR and X-ray diffraction: monoclinic, a = 20.138(3), b = 10.831(1), c = 14.973(2) angstrom, beta = 98.04(1)-de grees, Z = 4, space group P2(1)/c, R = 0.032. The compound is dimeric with the two [Pd(N,N-dimethylbenzylamine)]moieties being connected by the two vicinal bridging eta2-N,S-quinoline-2-thiolate anions in a squ are-planar coordination geometry for the palladium atoms.