A SHORT SYNTHESIS OF ENANTIOMERICALLY PURE (-ELDANOLIDE AND ()-CIS-WHISKEY LACTONE BY SAMARIUM DIIODIDE PROMOTED FRAGMENTATION OF GAMMA-HALO ESTERS())

Authors
HONDA T YAMANE S NAITO K SUZUKI Y
Citation
T. Honda et al., A SHORT SYNTHESIS OF ENANTIOMERICALLY PURE (-ELDANOLIDE AND ()-CIS-WHISKEY LACTONE BY SAMARIUM DIIODIDE PROMOTED FRAGMENTATION OF GAMMA-HALO ESTERS()), Heterocycles, 37(1), 1994, pp. 515-521
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
37
Issue
1
Year of publication
1994
Pages
515 - 521
Database
ISI
SICI code
0385-5414(1994)37:1<515:ASSOEP>2.0.ZU;2-F
Abstract
A stereoselective synthesis of (+)-eldanolide and (-)-cis-whisky lacto ne in optically pure forms has been achieved by employing a regioselec tive fragmentation reaction of the gamma-halo esters as a key step.