CLEAVAGE OF BETA-KETOESTERS VIA IMINYL RADICALS - APPLICATION IN THE SYNTHESIS OF A SPIROLACTONE

Authors
SRIDAR V BABU G
Citation
V. Sridar et G. Babu, CLEAVAGE OF BETA-KETOESTERS VIA IMINYL RADICALS - APPLICATION IN THE SYNTHESIS OF A SPIROLACTONE, Synthetic communications, 27(2), 1997, pp. 323-330
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
27
Issue
2
Year of publication
1997
Pages
323 - 330
Database
ISI
SICI code
0039-7911(1997)27:2<323:COBVIR>2.0.ZU;2-#
Abstract
Reaction of Oximebenzoates of several beta-ketoesters with tributyltin hydride show beta-cleavage via an iminyl radical and application of t his results in the synthesis of a spirolactone.