REACTION OF SATURATED KETONES WITH A TRIVALENT URANIUM COMPLEX - ISOLATION AND CHARACTERIZATION OF THE ALCOHOLATE AND ENOLATE PRODUCTS

Authors
ADAM R VILLIERS C EPHRITIKHINE M
Citation
R. Adam et al., REACTION OF SATURATED KETONES WITH A TRIVALENT URANIUM COMPLEX - ISOLATION AND CHARACTERIZATION OF THE ALCOHOLATE AND ENOLATE PRODUCTS, Tetrahedron letters, 35(4), 1994, pp. 573-574
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
4
Year of publication
1994
Pages
573 - 574
Database
ISI
SICI code
0040-4039(1994)35:4<573:ROSKWA>2.0.ZU;2-J
Abstract
The uranium (III) complex Cp(3)U(THF)(Cp = eta - C5H5, THF=tetrahydrof uran) reacted with saturated ketones RCOCH(2)R' to give equimolar mixt ures of the compounds Cp(3)U-OCHR(CH(2)R') and Cp(3)U-OCR(=CHR').