TITANIUM (IV) CATALYSIS IN THE REDUCTION OF PHOSPHINE OXIDES

Authors
COUMBE T LAWRENCE NJ MUHAMMAD F
Citation
T. Coumbe et al., TITANIUM (IV) CATALYSIS IN THE REDUCTION OF PHOSPHINE OXIDES, Tetrahedron letters, 35(4), 1994, pp. 625-628
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
4
Year of publication
1994
Pages
625 - 628
Database
ISI
SICI code
0040-4039(1994)35:4<625:T(CITR>2.0.ZU;2-4
Abstract
Phosphine oxides can be reduced by triethoxysilane, or more convenient ly polymethylhydrosiloxane, and catalytic titanium (IV) isopropoxide a nd provides a system for the efficient one-pot generation of phosphoni um salts; the reduction occurs with retention of configuration at phos phorus.