A MECHANICAL MODEL FOR THE ONSET OF DAMAGE IN RUBBER-MODIFIED AMORPHOUS POLYMERS

At medium loading rates, void formation usually precedes plasticity in the matrix around the particles in rubber toughened polymers. Many au thors have proposed models for the relationship between rubber surface energy, volume strain energy and void growth. In this paper, it is sh own that another volume criterion must also be satisfied, arising from the fact that in all these models, no decohesion is allowed at the pa rticle-matrix interface. A fracture mechanics approach, where linear a nd non linear elasticity are assumed for the matrix and the rubber par ticle respectively, is used to define a void formation criterion depen ding on the rubber fracture surface energy. After formation, the stabi lity of the void is examined, taking into account the volume conservat ion between matrix and particle and the stress due to surface tension when the void size is very small. A size effect is observed, indicatin g that voids cannot grow in small particles. The required value of fra cture energy in a particle on a microscopic scale is discussed.