M. Barrera et al., POLARIGRAPHIC I-T CURVES AND NISHIHARA-MA TSUDA APPROXIMATION FOR THEKOUTECKY FUNCTION - APPLICATIONS, Anales de quimica, 89(4), 1993, pp. 493-496
From Nishihara-Matsuda results, we present the theoretical basis and e
xperimental verification of a novel method for determining thermodynam
ic and kinetic parameters of quasi-reversible single electrode process
es on a DME. The necessary experimental records are i-t curves at a gi
ven potencial. The chosen experimental system was maleic acid-BR buffe
r-NaCl 0.5M ionic strength and 25 degrees C.