A novel optical technique is used to investigate the dynamics of coagu
lation of particle suspensions with aluminum salt. The relative size o
f aggregates formed during coagulation, expressed as a ''coagulation i
ndex,'' can be continuously measured by this technique. Coagulation of
clay particles with aluminum sulfate is examined at various aluminum
concentrations, solution pH, and mixing intensities. Results indicate
that the coagulation index provides valuable information about aggrega
te dynamics and coagulation mechanisms with aluminum salts.