THE USE OF SILYL ENOL ETHERS IN THE ALKYLATION OF SUBSTITUTED CYCLANONES

Citation
P. Angers et P. Canonne, THE USE OF SILYL ENOL ETHERS IN THE ALKYLATION OF SUBSTITUTED CYCLANONES, Tetrahedron letters, 35(3), 1994, pp. 367-370
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
35
Issue
3
Year of publication
1994
Pages
367 - 370
Database
ISI
SICI code
0040-4039(1994)35:3<367:TUOSEE>2.0.ZU;2-O
Abstract
The reactions of 1-(trimethylsiloxy)-3-methylcyclopent-1-ene, 1-(trime thylsiloxy)-3-methylcyclohex-1-ene and 1-(trimethylsiloxy)-3,3-dimethy lcyclohex-1-ene with various alkylating agents in the presence of silv er trifluoroacetate produced the corresponding a,3-dialkylated and 2,3 ,3-trialkylated cyclanones with high regiodifferentiation and stereose lection.