THE USE OF SILYL ENOL ETHERS IN THE ALKYLATION OF SUBSTITUTED CYCLANONES

Authors
ANGERS P CANONNE P
Citation
P. Angers et P. Canonne, THE USE OF SILYL ENOL ETHERS IN THE ALKYLATION OF SUBSTITUTED CYCLANONES, Tetrahedron letters, 35(3), 1994, pp. 367-370
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
3
Year of publication
1994
Pages
367 - 370
Database
ISI
SICI code
0040-4039(1994)35:3<367:TUOSEE>2.0.ZU;2-O
Abstract
The reactions of 1-(trimethylsiloxy)-3-methylcyclopent-1-ene, 1-(trime thylsiloxy)-3-methylcyclohex-1-ene and 1-(trimethylsiloxy)-3,3-dimethy lcyclohex-1-ene with various alkylating agents in the presence of silv er trifluoroacetate produced the corresponding a,3-dialkylated and 2,3 ,3-trialkylated cyclanones with high regiodifferentiation and stereose lection.