SUBSTITUENT EFFECT ON THE CHEMICAL BEHAVIOR OF SOME CARBONYL-COMPOUNDS AND KETALS WITH 1-ETHOXY-3-TRIMETHYLSILYLPROP-1-YNE

Authors
ZAKARYA D RAYADH A SAMIH M LAKHLIFI T
Citation
D. Zakarya et al., SUBSTITUENT EFFECT ON THE CHEMICAL BEHAVIOR OF SOME CARBONYL-COMPOUNDS AND KETALS WITH 1-ETHOXY-3-TRIMETHYLSILYLPROP-1-YNE, Tetrahedron letters, 35(3), 1994, pp. 405-408
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
3
Year of publication
1994
Pages
405 - 408
Database
ISI
SICI code
0040-4039(1994)35:3<405:SEOTCB>2.0.ZU;2-Q
Abstract
In this work, principal component analysis (PCA) was carried out on (h e basis of property descriptors far a set of carbonyl compounds and ke tals. A principal component projection of the points representing the compounds showed Bat the chemical behaviour of the compounds with 1-et hoxy-3-trimethylsilylprop-1-yne is related to their chemical compositi on. The obtained structure-chemical behaviour information was used to design a space transition state of the studied reactions.