HIGHLY SELECTIVE SYNTHESIS OF 4-VINYLCYCLOHEXENE BY CYCLODIMERIZATIONOF BUTADIENE CATALYZED BY AMINOPHOSPHINEPHOSPHINITE AND BIS(AMINOPHOSPHINE) CHIRAL LIGANDS NICKEL-COMPLEXES
I. Suisse et al., HIGHLY SELECTIVE SYNTHESIS OF 4-VINYLCYCLOHEXENE BY CYCLODIMERIZATIONOF BUTADIENE CATALYZED BY AMINOPHOSPHINEPHOSPHINITE AND BIS(AMINOPHOSPHINE) CHIRAL LIGANDS NICKEL-COMPLEXES, Tetrahedron letters, 35(3), 1994, pp. 413-416
The highest chemoselective synthesis of 4-vinylcyclohexene ever observ
ed by butadiene cyclodimerization on nickel complexes has been obtaine
d with aminophosphinephosphinite and bis(aminophosphine) chiral ligand
s (selectivity up to 99%).