CATALYTIC-OXIDATION OF HOMOALLYLALCOHOLS TO ALPHA-ALKOXYTETRAHYDROFURANS BY A PD-NITRO COMPLEX AND MOLECULAR-OXYGEN

Authors
MEULEMANS TM KIERS NH FERINGA BL VANLEEUWEN PWNM
Citation
Tm. Meulemans et al., CATALYTIC-OXIDATION OF HOMOALLYLALCOHOLS TO ALPHA-ALKOXYTETRAHYDROFURANS BY A PD-NITRO COMPLEX AND MOLECULAR-OXYGEN, Tetrahedron letters, 35(3), 1994, pp. 455-458
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
3
Year of publication
1994
Pages
455 - 458
Database
ISI
SICI code
0040-4039(1994)35:3<455:COHTA>2.0.ZU;2-2
Abstract
Various homoallylalcohols were highly regioselective oxidized with mol ecular oxygen at the terminal carbon to afford cyclic acetals (alpha-a lkoxytetrahydrofurans) using PdNO2Cl(CH3CN)(2) as a catalyst in the pr esence of CuCl2 and t-butanol or isopropanol.