A microstructural study of YBCO thin films grown on Si with MgO as a b
uffer layer by the rf magnetron sputtering method combined with the ho
t-wall sputtering method has been carried out. The structure of the th
in films were investigated by XRD and TEM. The highly c-oriented YBCO
thin films on the polycrystalline MgO buffer layer were found. However
, around the interface between YBCO and MgO the orientation of YBCO is
a-oriented rather than c-oriented, and the interface between MgO and
Si is an amorphous oxide layer, the polycrystalline MgO was found abov
e the oxide layer. The relationship between the superconducting proper
ty and the interface microstructure is also be discussed.