Spherical particulates in fly ash from two bituminous coals, two subbi
tuminous coals and one lignite have been studied by interference contr
ast polarized light microscopy (ICT-PLM) and scanning electron microsc
opy with energy dispersive X-ray spectroscopy (SEM-EDS). Most of the g
lassy spheres were between 8 and 50 mu m in diameter. Second phase mat
erial was seen on many of the solid sphere surfaces. Microspheres atta
ched to the surfaces of larger spheres were found to have different co
mpositions from that of the host sphere. Microparticulate capture by t
he larger spheres is a phenomenon that needs more study before the cap
ture mechanism and its efficiency can be understood.