J. Harms et al., DROPLETS FORMED IN HELIUM FREE-JET EXPANSIONS FROM STATES NEAR THE CRITICAL-POINT, The Journal of chemical physics, 106(8), 1997, pp. 3348-3357
Droplets formed in He-4 free jets expanded from source stagnation stat
es in the vicinity of the critical point (T-c=5.2 K, P-c=2.3 bar) are
investigated using a mass-spectrometer time-of-flight (TOF) technique.
Depending on the source conditions, three different TOF peaks are ide
ntified: (a) atoms, (b) droplets formed by condensation from the gas p
hase, and (c) droplets formed by disintegration of the liquid phase. T
he latter show the lowest ever observed He-4 cluster speeds, about 50
m/s, at a source pressure of 1.5 bar and a source temperature of 4-5 K
, just below the critical pressure and temperature. The TOF distributi
ons at the critical point are very broad and this may be due to critic
al-point fluctuations during the averaging period (2-10 min) of the in
dividual measurements. (C) 1997 American Institute of Physics.