Sb. Shah et al., FENTONS REAGENT-INITIATED CRAFT COPOLYMERIZATION OF ACRYLONITRILE ONTO SODIUM ALGINATE, Journal of applied polymer science, 51(8), 1994, pp. 1421-1426
Graft copolymerization of acrylonitrile (AN) onto sodium alginate was
studied in an aqueous medium using ferrous ammonium sulfate-hydrogen p
eroxide (Fenton's reagent) as the redox initiator. To optimize the rea
ction conditions for affording maximum percentage of grafting, the con
centrations of sulfuric acid, initiator components, monomer, and also
temperature and time were varied. The results are discussed and a reac
tion mechanism is proposed. (C) 1994 John Wiley & Sons, Inc.