We have performed hydrogen diffusion experiments in a-Si:H p-i-n diode
s subjected to a constant and to a pulsed reverse electric field. Unde
r a reverse field, the mean-free-path for diffusion of interstitial hy
drogen is enhanced by a factor of at least similar to 4. The results p
resented here indicate that the enhancement is not due to the field-dr
ift of charged hydrogen atoms, but rather to the reduction in electron
ic carrier density under reverse bias. The carriers control the captur
e rate of interstitial hydrogen into Si-H traps and, therefore, the li
fetime and the mean-free-path for diffusion through interstitials.