We present real-time and in situ atomic force microscope (AFM) observa
tions of solution growth on the cleavage plane of two minerals, calcit
e and fluorite. Different growth behaviours are exhibited: the calcite
surface grows via a layer-spiral mechanism, while the fluorite surfac
e grows via the formation of sharp asperities. The difference in behav
iour of the two minerals may be linked to the lack of local charge neu
trality on the fluorite surface. The growth mechanisms observed on cal
cite and fluorite provide insight into the expected behaviour of a wid
e range of salts important in nature and industry.