ALLYL MAGNESIUM COMPOUNDS AS SYMMETRICAL AND ASYMMETRIC FUNCTIONALIZATION AGENTS IN POSITIONS 2 AND 5 OF 1,3,4-THIADIAZOLE

Authors
LADURANTY J MIGINIAC L
Citation
J. Laduranty et L. Miginiac, ALLYL MAGNESIUM COMPOUNDS AS SYMMETRICAL AND ASYMMETRIC FUNCTIONALIZATION AGENTS IN POSITIONS 2 AND 5 OF 1,3,4-THIADIAZOLE, Journal of organometallic chemistry, 464(1), 1994, pp. 1-9
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
464
Issue
1
Year of publication
1994
Pages
1 - 9
Database
ISI
SICI code
0022-328X(1994)464:1<1:AMCASA>2.0.ZU;2-T
Abstract
Allylic Grignard reagents easily react through addition and eliminatio n, with the two methylthio groups of 2,5-bis(methylthio)-1,3,4-thiadia zole, and with the one methylthio group of 5-methylthio-1,3,4-thiadiaz ol-2(3H)-thione, to lead to symmetrical or unsymmetrical disubstituted derivatives of 1,3,4-thiadiazole.