CONVERGENT SYNTHESIS OF AMINOBICYCLO[3.3.0]OCTENES USING ZIRCONIUM CHEMISTRY - AN UNUSUAL ANTI-1,3-AMINE SHIFT

Authors
DAVIS JM WHITBY RJ JAXACHAMIEC A
Citation
Jm. Davis et al., CONVERGENT SYNTHESIS OF AMINOBICYCLO[3.3.0]OCTENES USING ZIRCONIUM CHEMISTRY - AN UNUSUAL ANTI-1,3-AMINE SHIFT, Synlett, (2), 1994, pp. 110-112
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
2
Year of publication
1994
Pages
110 - 112
Database
ISI
SICI code
0936-5214(1994):2<110:CSOAUZ>2.0.ZU;2-N
Abstract
Insertion of phenyl isocyanide into zirconacyclopentenes affords imino acyl complexes which rearrange to give alpha,beta-unsaturated zirconoc ene eta2-imine complexes. These insert alkenes or alkynes to afford el aborated cyclopentenylamines on protic work-up. The products undergo a facile anti-1,3-amine-shift to afford 1-anilinobicyclo[3.3.0]oct-2-en es.