ELECTRON-PARAMAGNETIC-RESONANCE INVESTIGATIONS OF THE EFFECT OF HYDROPHILIC AND FLEXIBLE CROSS-LINKING ON THE COORDINATION STRUCTURES OF COPPER-COMPLEXES OF TRIETHYLENEGLYCOL DIMETHACRYLATE-CROSS-LINKED AMINOPOLYACRYLAMIDES

Authors
JOSE L MATHEW B PILLAI VNR
Citation
L. Jose et al., ELECTRON-PARAMAGNETIC-RESONANCE INVESTIGATIONS OF THE EFFECT OF HYDROPHILIC AND FLEXIBLE CROSS-LINKING ON THE COORDINATION STRUCTURES OF COPPER-COMPLEXES OF TRIETHYLENEGLYCOL DIMETHACRYLATE-CROSS-LINKED AMINOPOLYACRYLAMIDES, Polymer, 34(18), 1993, pp. 3963-3965
Citations number
18
Categorie Soggetti
Polymer Sciences
Journal title
Polymer → ACNP
ISSN journal
00323861
Volume
34
Issue
18
Year of publication
1993
Pages
3963 - 3965
Database
ISI
SICI code
0032-3861(1993)34:18<3963:EIOTEO>2.0.ZU;2-0
Abstract
Copper(II) complexation of amino functions supported on triethylenegly col dimethacrylate-crosslinked polyacrylamides in varying structural e nvironments was investigated. The electron parametic resonance spectru m is used to probe the coordination structure and the nature of the Cu -N bond of the derived aminopolyacrylamide-Cu(II) complexes. The exten t of the hydrophilic and flexible crosslinking agent in the macromolec ular matrix has a significant effect on the coordination structure of the complexes.