Qx. Jia et al., MICROSTRUCTURE OF BA0.5SR0.5TIO3 THIN-FILMS ON (100)LAALO3 WITH SRRUO3 AS ELECTRODES, Philosophical magazine. B. Physics of condensed matter. Statistical mechanics, electronic, optical and magnetic, 75(2), 1997, pp. 261-269
Using pulsed-laser deposition, we grew quaternary Ba0.5Sr0.5TiO3 thin
films heteroepitaxially on (100) LaAlO3 substrates with conductive SrR
uO3 as a bottom electrode. The microstructure of this multilayer of Ba
0.5Sr0.5TiO3/SrRuO3/LaAlO3, was characterized by X-ray diffraction and
cross-sectional transmission electron microscopy. The heteroepitaxial
growth relationship was found to be (h00)(Ba0.5Sr0.5TiO3)parallel to(
00l)(SrRuO3)parallel to(h00)(LaAlO3) and [110](Ba0.5Sr0.5TiO3)parallel
to [100](SrRuO3)parallel to[110](LaAlO3). The high dielectric constan
t of the crystalline Ba0.5Sr0.5TiO3 thin films and the low leakage cur
rent of the Ba0.5Sr0.5TiO3 film sandwiched between a top Au and bottom
SrRuO3 electrodes are attributed to the structural perfection of the
films and the clean interfaces between layers.