We report on results on the sensitization of TiO2 using a-Si:H as a se
nsitizer. Employing a sol-gel method colloidal TiO2 films with large a
nd topologically rough surfaces have been prepared. A-Si:H films were
deposited on top of the set-gel firms serving as optical absorber and
electron injector. Interface structure, carrier transfer across the in
terface and transport through the TiO2 were studied. Applications for
a photovoltaic device are discussed.