The various tools for flow visualization have been significantly expan
ded over the past several years through the use of molecular scatterin
g and molecular laser-induced fluorescence. These approaches have adde
d the capability of sampling individual small volume elements within a
flow, and by using cameras for detection, they are easily extended to
sample Lines and cross-sectional planes. This localized measurement c
apability means that these approaches can be made quantitative even in
complex and/or unsteady flow fields. If the molecular species is natu
rally occurring, such as oxygen or nitrogen in air, then no seeding is
required. Furthermore, in these applications, images of the flow can
be frozen in time by using a short pulse laser for illumination. The d
istribution of the molecules reflects the true physics of the flow, so
even raw images taken in this manner give an immediate understanding
of flow field properties. With proper calibration, the images can be f
urther analyzed to yield quantitative information about the how. In th
e case of flow tagging, the analysis gives velocity profiles when line
s are written, and deformation, vorticity, and dilation with grid patt
erns. Molecular scattering can be used to give quantitative values of
density, temperature, and two-dimensional velocity. This paper present
s three such molecular-based approaches: laser-induced fluorescence fr
om oxygen, flow tagging by oxygen excitation, and Rayleigh scattering.
These three approaches are chosen because all three can be used in na
turally occurring air with no seeding. The raw data from each of these
approaches gives an immediate appreciation of the flow structure and
further analysis yields accurate values of velocity, temperature, and
density. These approaches use readily available laser sources; however
, they will: be greatly enhanced with new source technologies that are
currently under development.