MOSSBAUER STUDIES OF HETEROBIMETALLIC AND HETEROTRIMETALLIC COMPOUNDSCONTAINING IRON AND TIN

Citation
Gm. Delima et al., MOSSBAUER STUDIES OF HETEROBIMETALLIC AND HETEROTRIMETALLIC COMPOUNDSCONTAINING IRON AND TIN, Hyperfine interactions, 83(1-4), 1994, pp. 183-189
Citations number
8
Categorie Soggetti
Physics, Atomic, Molecular & Chemical","Physics, Nuclear","Physics, Condensed Matter
Journal title
ISSN journal
03043843
Volume
83
Issue
1-4
Year of publication
1994
Pages
183 - 189
Database
ISI
SICI code
0304-3843(1994)83:1-4<183:MSOHAH>2.0.ZU;2-Y
Abstract
A series of ferrocene derivatives was prepared and studied by Fe-57 an d Sn-119 Mossbauer spectroscopy, as well as by other techniques such a s NMR and IR spectroscopies. These complexes can be divided into three types: mercurated, organotin derivatives of ferrocene, and bi- and tr imetallic derivatives of 1,1'-bis(diphenylphosphino)ferrocene. Iron di d not show great variation in its Mossbauer parameters in the compound s, in spite of their diversity; tin, however, gave important Mossbauer data for the elucidation of bonding and structural features of the co mplexes.