Gm. Delima et al., MOSSBAUER STUDIES OF HETEROBIMETALLIC AND HETEROTRIMETALLIC COMPOUNDSCONTAINING IRON AND TIN, Hyperfine interactions, 83(1-4), 1994, pp. 183-189
A series of ferrocene derivatives was prepared and studied by Fe-57 an
d Sn-119 Mossbauer spectroscopy, as well as by other techniques such a
s NMR and IR spectroscopies. These complexes can be divided into three
types: mercurated, organotin derivatives of ferrocene, and bi- and tr
imetallic derivatives of 1,1'-bis(diphenylphosphino)ferrocene. Iron di
d not show great variation in its Mossbauer parameters in the compound
s, in spite of their diversity; tin, however, gave important Mossbauer
data for the elucidation of bonding and structural features of the co
mplexes.