Iv. Bondarenko et al., KINETICS OF TRANSITION OF GALLIUM INTO LIQUID-PHASE UPON INTERACTION OF GALLIUM-CONTAINING SODIUM HYDROALUMOCARBONATES WITH ALKALINE-SOLUTIONS, Russian metallurgy. Metally, (5), 1993, pp. 61-64
Regularities governing the rate of gallium transition into liquid phas
e upon break down of sodium hydroalumocarbonates are established. The
reaction is found to be of a diffusion nature. The entropy and enthalp
y of formation for the activated complex were calculated. The mechanis
m of interaction of gallium-containing sodium hydroalumocarbonates wit
h alkali solutions is discussed.