FABRICATION OF SOLID OXIDE FUEL-CELL ELEC TRODES BY PLASMA SPRAYING OF NI YSZ MECHANICALLY ALLOYED COMPOSITE POWDERS/

In order to fabricate SOFC fuel electrodes, which were composed of a f ine homogeneous microstructure of Ni/YSZ, plasma spraying of Ni/YSZ me chanically alloyed composite powders was carried out. To perform this, the oxidation heat treatments of the MA powder were introduced. Some properties, for example, conductivity and gas permeability, of the coa tings obtained were measured, and the applicability of MA powders to t he fuel electrodes was evaluated. The results obtained are summarized as follows: (1) The oxidation heat treatments to the MA powders were s eemed to be effective in both suppression of the separation between Ni and YSZ and maintenance of the initial composition of the powder. Fin e-microstructure fuel electrodes were fabricated by the spraying of pr e-oxidized MA powders. (2) The relation between conductivity of the co ating and reduction time at 1273 K was measured. In the coating made f rom 72 ks MA and 50%Ni contained powders, as the reduction time increa sed the conductivity increased gradually, and the conductivity of this coating reached the maximum value of 90 kS/m finally. (3) The gas per meability of the coatings made from MA powders were smaller than that of the coatings made from conventional agglomerated powders. This coul d be improved by controlling the process parameters such as spraying c onditions.