AN OBSERVATION OF BENZOTRIAZOLE (BTA) ADSORPTION ON CU(110) BY THE ULTRA-HIGH-VACUUM (UHV) SCANNING TUNNELING MICROSCOPE (STM) AND LOW-ENERGY-ELECTRON DIFFRACTION (LEED)
K. Cho et al., AN OBSERVATION OF BENZOTRIAZOLE (BTA) ADSORPTION ON CU(110) BY THE ULTRA-HIGH-VACUUM (UHV) SCANNING TUNNELING MICROSCOPE (STM) AND LOW-ENERGY-ELECTRON DIFFRACTION (LEED), JPN J A P 2, 33(1B), 1994, pp. 120000125-120000128
We have investigated Benzotriazole (BTA) adsorption structures and kin
etics on the clean Cu(110) and oxygen reconstructed Cu(110)-2 x 1 surf
aces. The first atomicaly resolved scanning tunneling microscope (STM)
images showed that BTA adsorbed on the clean Cu(110)-1 x 1 surface to
form the c(4 x 2) commensurate structure, agreeing the c(4 x 2) LEED
pattern. On the other hand, STM images of BTA adsorbed on the oxygen i
nduced Cu(110)-2 x 1 surface were a fully disordered structure. In kin
etic point of view, BTA molecules should adsorb preferentially on the
oxygen induced Cu(110)-2 x 1 missing row compared to the clean Cu(110)
surface.