DIETHYL ISOPROPHYL AND ISOPROPENYL PHOSPHATE VIA DIFFERENTLY GENERATED KETYL RADICALS OF ACETONE REACTING WITH DIETHYL PHOSPHORIC-ACID

Authors
SCHOLE J SCHOLE C EIKEMEYER J KREBS HC
Citation
J. Schole et al., DIETHYL ISOPROPHYL AND ISOPROPENYL PHOSPHATE VIA DIFFERENTLY GENERATED KETYL RADICALS OF ACETONE REACTING WITH DIETHYL PHOSPHORIC-ACID, Tetrahedron, 50(4), 1994, pp. 1125-1128
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
4
Year of publication
1994
Pages
1125 - 1128
Database
ISI
SICI code
0040-4020(1994)50:4<1125:DIAIPV>2.0.ZU;2-H
Abstract
Photochemically excited acetone reacts in 1,2-dimethoxy ethane with di ethyl phosphoric acid to diethyl isopropyl phosphate. The same product is formed by reduction of acetone with magnesium amalgam in benzene i n the presence the same phosphoric acid derivative. Thermal decomposit ion of tetramethyldioxetane in benzene in the presence of diethyl phos phoric acid appears to yield primarily diethyl isopropenyl phosphate.