Ra. Toth, LINE STRENGTHS (900-3600 CM(-1)), SELF-BROADENED LINEWIDTHS, AND FREQUENCY-SHIFTS (1800-2360 CM(-1)) OF N2O, Applied optics, 32(36), 1993, pp. 7326-7365
Self-broadened linewidths and pressure-induced frequency shifts of N2O
were measured from spectra obtained at high spectral resolution in th
e 1800-2630 cm(-1) region. From measurements of 136 Lines, the average
pressure-shift coefficient was found to be -0.0015 +/- 0.0006 cm(-1)/
atm. The shift coefficients were found to have a weak J dependence, in
which the magnitude of the coefficients increases with increasing val
ues of J. Line-strength measurements were derived from spectra obtaine
d at low sample pressures, and these data were analyzed to determine v
ibrational band strengths, rotationless dipole-moment matrix elements,
and F factor coefficients for several bands in the 900-3600 cm(-1) re
gion. Measurements of over 15,000 selected vibration-rotation transiti
ons, including eight N2O isotopic species, were used in the various an
alyses.