EPOXIDATION OF OLEFINS BY MOLECULAR-OXYGEN USING PERFLUOROCARBONS AS REACTION MEDIA

Authors
POZZI G MONTANARI F RISPENS MT
Citation
G. Pozzi et al., EPOXIDATION OF OLEFINS BY MOLECULAR-OXYGEN USING PERFLUOROCARBONS AS REACTION MEDIA, Synthetic communications, 27(3), 1997, pp. 447-452
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
27
Issue
3
Year of publication
1997
Pages
447 - 452
Database
ISI
SICI code
0039-7911(1997)27:3<447:EOOBMU>2.0.ZU;2-J
Abstract
Epoxidation of olefins by dioxygen in combination with aldehyde as red ucing agent can be carried out at room temperature, in the absence of metal catalysts, using perfluorocarbons as inert reaction media. These non-toxic, non ozone-depleting fluids are good alternatives to the ch lorinated solvents normally used.