SYNTHESIS OF FUSED CYCLOPENTENO-HETEROCYCLES AND CYCLOHEPTENO-HETEROCYCLES

Citation
Ge. Mertzanos et al., SYNTHESIS OF FUSED CYCLOPENTENO-HETEROCYCLES AND CYCLOHEPTENO-HETEROCYCLES, Synthetic communications, 27(3), 1997, pp. 493-505
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397911
Volume
27
Issue
3
Year of publication
1997
Pages
493 - 505
Database
ISI
SICI code
0039-7911(1997)27:3<493:SOFCAC>2.0.ZU;2-T
Abstract
Cyclopenteno-triazoles, pyrazoles and isoxazoles 3a-i were synthesized from the reaction of various bishalomethyl substrates 1a-e with compo unds containing active methylene groups 2a-c. In addition, seven membe red ketodiesters 11 were synthesized from the reaction of 1 with dimet hyl 3-oxoglutarate. Finally, from the ketodiester 11a the triazoleanne lated bicyclo-undecadiones 12 were formed under phase transfer catalys is.