REGIOSPECIFIC CARBOALKOXYLATION OF 2,5-DIBROMOPYRIDINE

Citation
Rj. Chambers et A. Marfat, REGIOSPECIFIC CARBOALKOXYLATION OF 2,5-DIBROMOPYRIDINE, Synthetic communications, 27(3), 1997, pp. 515-520
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397911
Volume
27
Issue
3
Year of publication
1997
Pages
515 - 520
Database
ISI
SICI code
0039-7911(1997)27:3<515:RCO2>2.0.ZU;2-6
Abstract
Carboalkoxylation of 2,5-dibromopyridine with carbon monoxide and an a lcohol in the presence of palladium acetate and 1,1'-bis(diphenyl-phos phino)ferrocene (dppf) occurs regiospecifically to afford esters of 5- bromo-pyridine-2-carboxylic acid in good yield.